Micromeritics AutoPore V

Density and porosimetry analysis for mesoporous and macroporous materials

Leading performance for mesoporous and macroporous materials coupled with class-leading operational safety.

  • Widest range of measurable pore sizes: from as 3 nm to 1100 µm
  • High resolution analysis for macroporous and mesoporous materials in both intrusion and extrusion analyses
  • New enhancements focus on improving operator safety
  • Flexible method definition optimizes for speed or resolution as needed
  • Powerful, customizable reporting system produces actionable measurement outputs
  • Complies with the ASTM Methods D4284, D4404, and D6761, as well as ISO 15901-1 and USP <267>
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Overview

The mercury porosimetry analysis technique is based on the intrusion of mercury into a porous structure under stringently controlled pressures. Besides offering speed, accuracy, and a wide measurement range, mercury porosimetry permits you to calculate numerous sample properties such as pore size distributions, total pore volume, total pore surface area, median pore diameter and sample densities (bulk and skeletal).

The AutoPore V Series Mercury Porosimeters can determine a broader pore size distribution more quickly and accurately than other methods. This instrument also features enhanced safety features and offers new data reduction and reporting choices that provide more information about pore geometry and the fluid transport characteristics of your material.

Features

  • Triple fail safe - 2 interlocks on locking caps

    Verifies that the capacitance detector is installed on low-pressure port, automatically suspends run, and permits user to check filling of the penetrometer prior to run

  • Mercury collection trays

    Safe collection of mercury for disposal in the case of compromised penetrometer seals or operator error resulting in broken penetrometers

  • Improved mercury funnel design

    Attached screw cap and funnel-shaped opening eliminates mercury contamination and possible drip-spillage associated with separate detached filling funnel. Attached screw cap prevents loose cap and possible vapor release

  • Mercury vapor detection device

    Handheld device to check localized mercury vapor levels that exceed defined safety limits. Portable device allows point checks at the instrument or any location within the lab exposed to mercury

Safety features

  • Triple Fail Safe - 1 Penetrometer Safety Cap: In case of operator error, this device prevents the penetrometer or rod being released from port unintentionally
  • Triple Fail Safe - 3 System Pressure Vent on Manifold: Works in concert with Cap Interlock to automatically vent system pressure if above ambient pressure and error condition is detected
  • Software Control for Fine Powder Samples: Prevents fine powder from accidental aspiration into low-pressure ports during analysis by using intelligent evacuation controlled by sample type

Applications

Porosity and surface area play major roles in the purification, processing, blending, tableting, and packaging of pharmaceutical products as well as a drug’s useful shelf life, its dissolution rate, and bio-availability.

Pore area and porosity affect the curing and bonding of greenware and influence strength, texture, appearance, and density of finished goods.

Knowledge of pore area, total pore volume, and pore size distribution is important for quality control of industrial adsorbents and in the development of separation processes. Porosity and surface area characteristics determine the selectivity of an adsorbent.

The active surface area and pore structure of catalysts influence production rates. Limiting the pore size allows only molecules of desired sizes to enter and exit, creating a selective catalyst that will produce primarily the desired product.

Surface area and porosity of heat shields and insulating materials affect weight and function.

Determine correct composition of catalyst supports and finished products including crystallinity, porosity, and formulation.

Fuel cell electrodes require controlled porosity with high surface area to produce adequate power density.

Porosity is important in groundwater hydrology and petroleum exploration because it relates to the quantity of fluid that a structure can contain as well as how much effort will be required to extract it.

Pore size, pore volume, pore shape, and pore tortuosity are of interest to filter manufacturers. Often, pore shape has a more direct effect upon filtration than pore size because it strongly correlates with filtration performance and fouling.

Diffusion, permeability, and capillary flow play important roles in the degradation processes in concrete, cement, and other construction materials.

The porosity of print media coating is important in offset printing where it affects blistering, ink receptivity, and ink holdout.

Surface area and porosity of heat shields and insulating materials affect weight and function.

Specification

General

Measurement range Low pressure (all models):
0.2 to 50 psia (345 kPa)

High pressure:
9600/9605: From atmospheric pressure to 33,000 psia
9610/9620: From atmospheric pressure to 60,000 psia
Pore size range
Low pressure (all models):
1100* to 3.6 µm (*calculated with initial filling pressure of 0.2 psia)
 
High pressure:
9600/9605: 6 to 0.005 µm
9610/9620: 6 to 0.003 µm
Resolution
Low pressure (all models):
0.00025 psia
 
High pressure: 
9600/9605: 0.165 psia from 3,300 psia to 33,000 psia
9610/9620: 0.03 psia from atmospheric pressure to 60,000 psia
Transducer accuracy
Low pressure (all models): +/- 1% of full scale
 
High pressure: +/-0.1% of full scale
Transducer hysteresis
Low pressure (all models)
 
High pressure: 0.05% of full scale
Servo control precision
Low pressure (all models): 1% of target, min 0.05 psia, no overshoot
 
High pressure: 0.5% of target, min 5 psia, no overshoot
Intrusion resolution
Better than 0.1 all
Intrusion accuracy
+/- 1% of maximum penetrometer stem volume
Gas Consumption
Nitrogen or other clean, dry gas at 50 psig (345 kPa)

Electrical

Voltage
100/120/220/240 VAC ± 10%
Frequency
50 or 60 Hz
Power
500 VA maximum

Physical

Dimensions (W, D, H)
54.3 (w) x 78 (d) x 143 (h) cm 
Weight
250 kg (500 lb)

Accessories

Complete your workflow

Mercury QuikVac

Mercury QuikVac is an excellent low-cost method for quickly containing mercury spills. 

The device is designed to be specifically useful in collecting those elusive mercury droplets and small mercury-contaminated particulate matter. 

Mercury is collected in a 250-mL recovery vessel and a replaceable 0.3 – 0.5 micron activated carbon filter assures that the device exhausts clean, safe air.

Mercury QuikVac

Penetrometer rack

Safely store and transport penetrometers to prevent breakage and unnecessary replacement.

Penetrometer rack

Penetrometers (partial list)

Model# Size Stem volume Medium Typical use
01 15 cc 0.392 Solid Refractories, low-porosity solid rocks/cores, low porosity solid polymers
02 15 cc 0.392 Powder Low-porosity powders, gravel, irregular rock shapes
03 15 cc 1.131 Solid Medium-porosity rocks/cores, solid materials
04 15 cc 1.131 Powder Medium-porosity rocks, solid materials, fumed silica
07 5 cc 0.392 Solid Paper, flexible polymer/membrane sheets, pharma tablets
08 5 cc 0.392 Powder Silicates, catalysts, powders (general use), pharma powders
09 5 cc 1.131 Solid Medium/high-porosity sheet-form materials (paper, polymer, etc.), pharma tablets
10 5 cc 1.131 Powder Silica-alumina, silicates, zeolites, catalysts, powders (general use), pharma powders
14 3 cc 0.412 Powder Powders (general use), materials with low quantity available
24 15 cc 3.263 Solid High-porosity rock/cores, low-density/high-porosity foams
25 15 cc 4.185 Solid High-porosity material with large volume

Operational advantages

  • Ability to measure pore diameters from 0.003 to 1100* µm *Calculated with an initial filling pressure of 0.2 psia (0.00128 MPa)
  • Controlled pressure can increase in increments as fine as 0.05 psia from 0.2 to 50 psia. This allows detailed data to be collected in the macropore region
  • High-resolution (sub-microliter) measurement of intrusion/extrusion volumes produces extraordinary precision allowing the development of tighter sample specifications, improved production processes, and high-quality research data
  • Operates in scanning and time- or rate-of-intrusion equilibrated modes
  • Real-time diagnostics provide knowledge of an issue before it becomes critical or impairs your analytical results
  • Collects extremely high-resolution data; better than 0.1 µL for mercury intrusion and extrusion volume
  • Improved linear motion for high-pressure chamber closure

Design advantages

  • Improved safety features reduce the risk of mercury spills and operator exposure
  • Available with four low- and two high-pressure ports for increased sample throughput
  • Available in 33,000 psia or 60,000 psia models
  • Low-noise, high-pressure generating system
  • A quick-scan mode allows a continuous pressure increase approximating equilibrium and providing faster screening
  • A choice of correction routine for baseline (automatic, differential, or manual) produces greater accuracy by correcting for compressibility and thermal effects caused by high pressure
  • Choice of pressure ramping methods lets you choose the scanning mode for high-speed or on-demand results, or equilibration mode for more accurate results with greater detail
  • Mercury temperature sensor allows automatic calculation of mercury density used for penetrometer calibrations
  • MicroActive software allows you to interactively manipulate data, define custom reports, and quickly achieve analytical results
  • Compensation for material compression under high-pressure analysis

Features and benefits

  • Provides rapid, detailed intrusion and extrusion analysis over a wide range of pore sizes
  • Nineteen standard penetrometer sizes and configurations allow analysis of a wide variety of sample sizes and shapes
  • New safety enhances set a new benchmark in operator safety
  • Scanning and equilibration modes of operation allow for rapid or more detailed analyses, respectively
  • MicroActive software allows for rapid modification of reporting ranges
  • Includes user-defined advanced reporting capabilities using Python scripts

Software

MicroActive software greatly improves the functionality, convenience, diagnostics, and data interpretation that establish the new standard for high-performance results in mercury porosimetry.

[Micromeritics autopore-miroactiv - software - Intelligent, intuitive, interactive.png] Micromeritics autopore-miroactiv - software - Intelligent, intuitive, interactive.png

Build a method through an interactive step-by-step script. Eases method creation and new user introduction to the operation of the AutoPore V.

Unlike competitive systems that use mercury density at ambient temperature only, the AutoPore V automatically measures the actual mercury temperature for accurate density calculations under operation conditions.

[Micromeritics autopore V - Mercury density calculation software.jpg] Micromeritics autopore V - Mercury density calculation software.jpg

You can quickly create custom advanced reports to meet your specific needs using Python scripting. New report options permit automatic report conversion to PDF or spreadsheet formats.

Allows analysis parameters (stem volume, maximum head pressure, pen constant) to be changed or corrected post analysis, eliminating re-running samples due to error.

Receive information on the distribution of pore shape. The method yields a three-dimensional array of cavity size and throat size vs. volume.

Real-time monitoring of critical system components for preventative maintenance and trouble shooting.

[Micromeritics autopore V - Diagnostic Dashboard software.jpg] Micromeritics autopore V - Diagnostic Dashboard software.jpg

Warnings are supplied automatically when suspect data are collected.

Pore volume, pore area, and pore size plots are available as well as the ability to calculate total intrusion volume, total pore (surface) area, median pore diameters, average pore diameters, bulk or envelope density, and apparent (skeletal) density.

[Micromeritics autopore V - Variety of available plots software.png] Micromeritics autopore V - Variety of available plots software.png

Simplifies penetrometer calibration through automated calculations either volumetrically or gravimetrically.

[Micromeritics autopore V - Enhanced penetrometer calibration software.png] Micromeritics autopore V - Enhanced penetrometer calibration software.png

MicroActive for Autopore V provides the ability to overlay up to 20 runs. Included is the option to import pore size distributions from gas adsorption isotherms to provide analysis data in the micro to macropore range in a single report.

Reports include:

  • Summary
  • Tabular Report
  • Cumulative Volume vs Size
  • Incremental Volume vs Size
  • Cumulative Area vs Size
  • Cumulative Volume vs Pressure
  • Incremental Volume vs Pressure
  • Differential Volume vs Size 1
  • Log Difference Volume vs Size
  • Differential Reference % Volume vs Size
  • Out Spec. % Volume vs Pressure
  • Differential Volume vs Size 2
  • Material Compressibility
  • Cavity to Throat Size Ratio
  • Fractal Dimension
  • Mayer-Stowe Particle Size
  • Tortuousity
  • Permeability
  • Reverberi
  • Advanced Report System

User manuals

Please contact support for the latest user manuals.

Software downloads

Please contact support for the latest software version.

Winning performance meets class-leading safety.

Winning performance meets class-leading safety.

Flexible method definition. Powerful reporting. Make detailed mesoporous and macroporous material analysis and reporting simple.

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