Water Treatment

Measuring zeta potential to aid water clarification

Download brochure

Importance of water treatment

For the water industry product quality is non-negotiable and demonstrating consistent compliance is essential. However, many facilities lack the capability to respond quickly and efficiently to fluctuations in raw water quality. Maintaining stable operation at all times, even in the event of significant process change. Reducing chemical dosage levels and sludge production reduces water treatment costs.

Malvern Panalytical offers fit-for-purpose, robust, fully automated systems for monitoring charge neutralization processes. These measure zeta potential, a parameter that directly quantifies the tendency of suspended particles to coagulate and sediment. This technology enables predictive control of the water clarification processes that precede all other water treatment steps. In this way, zeta potential measurements set a firm foundation for quality control while at the same time supporting the optimization of chemical flocculant addition.

Our Solutions

Zetasizer Lab

The world’s most widely-used systems for nanoparticle, colloid and protein size and charge measurements
Zetasizer Lab

Different steps in the water treatment process

Zetasizer Lab

Zetasizer Lab

Classic side scatter particle size and zeta potential analyzer with enhance...

Effective water treatment is crucial for ensuring clean, safe water. The process involves several key steps, each essential for removing impurities and ensuring water quality. Here’s a brief overview of the water treatment process and how Malvern Panalytical’s Zetasizer Lab technology can support in each stage:

1. Coagulation

Coagulation is the first step in water treatment, where chemicals (coagulants) are added to destabilize and aggregate suspended particles into larger clusters, known as flocs. These larger particles are easier to remove in subsequent steps. 

How the Zetasizer Lab can help? 

The Zetasizer Lab provides precise measurements of particle size and zeta potential. By analyzing these parameters, operators can optimize the dosage and type of coagulants, ensuring more effective coagulation and reducing chemical consumption.

2. Flocculation

Following coagulation, flocculation involves gently stirring the water to encourage the formation of flocs into larger, more manageable clusters. This step increases the efficiency of sedimentation. 

How the Zetasizer Lab can help? 

With real-time particle size analysis from the Zetasizer Lab, operators can monitor the growth and formation of flocs. This data allows for fine-tuning of the flocculation process, enhancing floc formation and improving the overall efficiency of the treatment.

3. Sedimentation

Sedimentation allows the flocs to settle at the bottom of the treatment tanks, separating them from the clearer water above. This step is crucial for removing the bulk of the suspended solids. 

How the Zetasizer Lab can help? 

The Zetasizer Lab can track changes in particle size and distribution throughout sedimentation. This information helps optimize the settling process by adjusting conditions to maximize floc removal and minimize the need for further processing.

4. Filtration

After sedimentation, the water undergoes filtration to remove any remaining particles and impurities. Filtration systems use various media, such as sand or activated carbon, to trap contaminants. 

How the Zetasizer Lab can help? 

The Zetasizer Lab’s ability to measure particle size and distribution can ensure that the filtration media is effectively capturing particles of specific sizes. By analyzing the efficiency of filtration, adjustments can be made to improve the overall effectiveness and longevity of the filtration media.

5. Disinfection

The final step in water treatment is disinfection, which involves killing or inactivating pathogens to ensure the water is safe for consumption. This is typically achieved through chemical disinfectants like chlorine or ultraviolet (UV) light. 

How the Zetasizer Lab can help? 

The Zetasizer can monitor any residual particles or potential contaminants that might affect disinfection efficacy. By ensuring the water is free from interfering substances, operators can enhance the effectiveness of disinfection processes and ensure regulatory compliance.

Common challenges in water treatment

Water treatment is a complex process with numerous challenges that can impact efficiency and effectiveness. Malvern Panalytical’s Zetasizer Lab technology can play a crucial role in overcoming these challenges, ensuring a more reliable and efficient treatment process. 

Common challenges include:

  • Variability in Water Quality
    Water sources often exhibit significant variability in quality due to changes in environmental conditions, pollution levels, or seasonal factors. This variability can affect the effectiveness of each treatment stage, from coagulation to disinfection.

    The Zetasizer Lab provides real-time analysis of particle size and zeta potential, enabling precise monitoring of water quality fluctuations. By offering detailed insights into particle characteristics, the Zetasizer Lab allows for rapid adjustments to treatment processes, ensuring consistent performance despite variations in water quality.

  • Inefficient Coagulation and Flocculation
    Achieving optimal coagulation and flocculation can be challenging, especially with varying types of impurities and particle sizes. Ineffective coagulation can lead to poor floc formation, reducing the efficiency of subsequent stages.

    The Zetasizer Lab’s capability to measure zeta potential and particle size distribution helps in selecting the right coagulants and optimizing dosages. By analyzing floc characteristics, the Zetasizer Lab ensures effective coagulation and flocculation, improving the overall efficiency of these critical steps.

  • Inconsistent Sedimentation Performance
    The sedimentation process can be hindered by poorly formed flocs or the presence of fine particles that do not settle effectively. Inconsistent sedimentation can lead to higher residual turbidity and increased load on filtration systems.

    The Zetasizer Lab can help monitor and evaluate particle size and distribution during sedimentation. By providing data on floc size and stability, it aids in optimizing sedimentation conditions and enhancing floc removal, leading to more reliable and efficient sedimentation.

  • Filter Fouling and Reduced Efficiency
    Over time, filtration media can become fouled by accumulated particles and impurities, reducing its effectiveness and requiring frequent maintenance or replacement. This can lead to increased operational costs and downtime.

    Using the Zetasizer Lab to analyze particle size and distribution can help in understanding the nature of particles captured by filters. This information can guide adjustments to filtration conditions and media selection, helping to minimize fouling and extend the lifespan of filtration systems.

  • Ensuring Effective Disinfection
    The effectiveness of disinfection processes can be compromised by the presence of residual particles or certain types of contaminants that interfere with disinfectant action. Inadequate disinfection can pose risks to water safety and compliance with regulatory standards.

    The Zetasizer Lab’s ability to monitor residual particles and assess water clarity ensures that the disinfection process is not hindered by contaminants. By providing insights into particle characteristics that may affect disinfection, the Zetasizer Lab helps in optimizing the use of disinfectants and achieving higher standards of water safety.

By addressing these challenges with Zetasizer measurement technology, water treatment facilities can enhance their process efficiency, reduce operational costs, and ensure high-quality water output. Malvern Panalytical’s advanced analytics provide the precision and insights needed to overcome common obstacles and achieve superior treatment performance.

Our zeta potential water treatment analysis solutions

Zeta potential measurement technology can be used in the laboratory for the off-line study and optimization of flocculation/coagulation processes. Advantages relative to traditional techniques include:

  • Speed of measurement
  • Ease of use
  • Reproducibility - not subject to operator-to-operator variability

Furthermore, zeta potential measurement can be implemented online, offering the opportunity for regular monitoring with no manual input, and for automated control. The demonstrated benefits of continuous measurement with an online system are:

  • Improved process stability
  • The ability to respond rapidly and proactively to changes in raw water and plant conditions
  • A reduction in chemical coagulant costs – 15-20% reported by users
  • Clear and precise information to guide operator decision making and/or a data stream via OPC, Modbus TCP/IP or 4-20 mA for automated plant control

Our Solutions

Zetasizer Lab

The world’s most widely-used systems for nanoparticle, colloid and protein size and charge measurements
Zetasizer Lab

Featured content