Pulse chemisorption with AutoChem II 2920: isopropylamine on zeolites

Several ZSM-5 zeolite samples were analyzed using the AutoChem II 2920. By pulsing isopropyl amine onto the zeolites, the concentration of acid sites can be determined for a particular zeolite. This is very important for catalytic reactions. For example, the reaction that occurred during these analyses proceeded through an intermediate due to an acid-base reaction between the amine and the zeolite, followed by a specific type of E2 elimination, known as the Hoffman elimination. Due to the second order kinetics involved in this reaction, a high concentration of acid sites would allow the reaction to proceed much more quickly.

Please download to read more.

ダウンロード アプリケーションノート